Stereoselective Synthesis of Dienes from N-Allylhydrazones
- 10 December 2008
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 11 (2) , 465-468
- https://doi.org/10.1021/ol802585r
Abstract
A new method for the stereoselective synthesis of dienes from aldehydes and N-allylhydrazine derivatives has been developed. High levels of (E)-stereoselectivity are obtained for a variety of substrates. Addition of a dienophile to the reaction mixture allows a one-flask diene synthesis−cycloaddition sequence.This publication has 20 references indexed in Scilit:
- Tandem Carbon−Carbon and Carbon−Chlorine Bond Formation by Cu(II) Chloride-Promoted [3,3] Sigmatropic Rearrangement of N-AllylhydrazonesJournal of the American Chemical Society, 2008
- Rare-Earth Metals and Aluminum Getting Close in Ziegler-Type OrganometallicsPublished by Springer Nature ,2006
- Neodymium-Based Ziegler/Natta Catalysts and their Application in Diene PolymerizationPublished by Springer Nature ,2006
- Palladium-Catalyzed Cross-Coupling Reactions in Total SynthesisAngewandte Chemie International Edition in English, 2005
- Enyne Metathesis (Enyne Bond Reorganization)Chemical Reviews, 2004
- The modified Julia olefination: alkene synthesis via the condensation of metallated heteroarylalkylsulfones with carbonyl compoundsJournal of the Chemical Society, Perkin Transactions 1, 2002
- The Diels-Alder Reaction in Total SynthesisAngewandte Chemie International Edition in English, 2002
- The Wittig olefination reaction and modifications involving phosphoryl-stabilized carbanions. Stereochemistry, mechanism, and selected synthetic aspectsChemical Reviews, 1989
- Direct, stereoselective synthesis of either - or -1,3-dienesTetrahedron Letters, 1983
- An Effusion Study of the Decomposition of Copper(II) BromideThe Journal of Physical Chemistry, 1964