stilt and the Pb/(Zr/Ti) displacement order parameters in Zr-rich sfrom 20 to 500 K
- 1 March 1997
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 55 (10) , 6174-6179
- https://doi.org/10.1103/physrevb.55.6174
Abstract
Neutron diffraction and dielectric data have been collected from a polycrystalline sample of (x=0.035) to determine the temperature dependence of the two-order parameters associated with the oxygen octahedral tilt and the Pb/(Zr/Ti) displacement, respectively, through the sequence of phase transitions - - present in this mixed system. The weak coupling between tilt and polarization (displacements) is satisfactorily described within the framework of a two-order-parameters statistical theory in which the respective effective fields involve two higher-order terms in addition to a linear term.
Keywords
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