Temperature- or Guest-Induced Drastic Single-Crystal-to-Single-Crystal Transformations of a Nanoporous Coordination Polymer
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- 23 September 2005
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 127 (41) , 14162-14163
- https://doi.org/10.1021/ja054913a
Abstract
Aside from a temperature-induced structural transformation, a new nanoporous coordination polymer [Ag6Cl(atz)4]·OH·6H2O (Hatz = 3-amino-1,2,4,-triazole) comprised of interpenetrated Ag3(atz)2 coordination nets exhibits a single-crystal-to-single-crystal transformation of a 5-fold to 6-fold net interpenetration change triggered by guest desorption/absorption.Keywords
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