Sound Measurements in Liquid and Solid , , and - Mixtures
- 8 July 1966
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 147 (1) , 185-197
- https://doi.org/10.1103/physrev.147.185
Abstract
Using the ultrasonic pulse technique at a carrier frequency of 10 Mc/sec, we have measured the longitudinal velocity of sound in liquid and solid , , and - mixtures (0.0, 5.03, 25.0, 74.9, 98.00, 99.84% ) in the temperature range from 1 to 4.2°K and the pressure range from 1 to 150 atm. An upper limit to the attenuation of sound in the region of the solid investigated is on the order of 0.3 to 0.7 . Values of the adiabatic compressibility of the liquid along the melting curve of are given. The discontinuity in the propagation velocity at a first-order phase boundary was utilized to locate the solidification curves of these samples and also to investigate the bcc-hcp crystallographic transition in solid samples, including pure , similar to that observed in pure by Grilly and Mills. The triple points for this transition in are given by °K, atm; °K, atm. The upper triple points for the mixtures lie on a straight line connecting and in temperature-pressure space. In addition, by observing the peak in the attenuation of sound, it was possible to measure the line in and in the 5.0% and 25.0% liquid mixtures. The upper point for pure is given by °K and atm. Comparison is made with existing data wherever possible.
Keywords
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