Resolving the Two-Electron Process for the Couple [(C5Me5)M(N∧N)Cl]+/[(C5Me5)M(N∧N)] (M = Rh, Ir) into Two One-Electron Steps Using the 2,2‘-Azobis(pyridine) N∧N Ligand, Fast Scan Cyclovoltammetry, and Spectroelectrochemistry: Detection of Radicals instead of MIIIntermediates
- 25 April 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 22 (11) , 2240-2244
- https://doi.org/10.1021/om020860j
Abstract
No abstract availableThis publication has 31 references indexed in Scilit:
- Metallorganische Komplexkationen [(ηn-CnR′n M(RN=CH-CH=NR)Cl]+ von 1,4-Diazabutadienen (M = Os und n = 6 oder M = Rh, Ir und n = 5, R = 2,6-Dialkylphenyl). Strukturen und Reduktion zu den Neutralverbindungen [(ηn-CnR′n)M(RN-CH=CH-NR)]Zeitschrift für anorganische und allgemeine Chemie, 2001
- Ligandengestützte Kopplung metallorganischer ReaktionszentrenAngewandte Chemie, 1997
- Chemical and Electrochemical Generation of Hydride-Forming Catalytic Intermediates (bpy)M(CnRn): M = Rh, Ir (n = 5); M = Ru, Os (n = 6). Coordinatively Unsaturated Ground State Models of MLCT Excited States?Inorganic Chemistry, 1994
- Photocatalysis. Mechanistic studies of homogeneous photochemical water gas shift reaction catalyzed under mild conditions by novel cationic iridium(III) complexesJournal of the American Chemical Society, 1993
- Formiat-getriebene, nicht-enzymatische NAD(P)H-Regeneration bei der durch Alkohol-Dehydrogenasen katalysierten stereoselektiven Reduktion von 4-Phenyl-2-butanonAngewandte Chemie, 1992
- Electrochemical kinetic discrimination of the single-electron-transfer events of a two-electron-transfer reaction: cyclic voltammetry of the reduction of the bis(hexamethylbenzene)ruthenium dicationJournal of the American Chemical Society, 1992
- Elektrochemische und pulsradiolytische Reduktion von (Pentamethylcyclopentadienyl)(polypyridyl)rhodium‐KomplexenEuropean Journal of Inorganic Chemistry, 1989
- Metallorganische Rhodium(III)-Komplexe als Homogenkatalysatoren für die Photoreduktion von Protonen zu Wasserstoff an kolloidalem TiO2Angewandte Chemie, 1987
- Organic reactions involving transition metals. Part I. Formation of pentamethylcyclopentadienylrhodium complexes by reaction of hexamethylbicyclo[2,2,0]hexa-2,5-diene with rhodium trichlorideJ. Chem. Soc. A, 1969
- Über einige Derivate und Oxydationsprodukte von 2‐Amino‐pyridinBerichte der deutschen chemischen Gesellschaft (A and B Series), 1927