Sulfur-containing Polymers. XIII. The Synthesis and Properties of Soluble Polydithiocarbamates
- 1 September 1974
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 47 (9) , 2287-2291
- https://doi.org/10.1246/bcsj.47.2287
Abstract
Polydithiocarbamates have been synthesized by the polycondensation of di-K or di-Na bisdithiocarbamates based on secondary diamines with bischloromethylated aromatics in N,N-dimethylformamide. The polymers obtained in good yields had inherent viscosities up to 0.66. The polymers derived from 1,3-di-4-piperidylpropane were soluble in organic solvents, such as dichloromethane and chloroform, and gave transparent, tough films from the solution. These polymers decomposed upon UV irradiation, with the liberation of carbon disulfide. The photopolymerization of methyl methacrylate in the presence of the polymer has also been studied.Keywords
This publication has 11 references indexed in Scilit:
- Sulfur‐containing polymers. X. Aromatic poly(sulfenyl thiocarbonates)Journal of Polymer Science: Polymer Chemistry Edition, 1973
- Sulfur‐containing polymers. VIII. Preparation and properties of poly(carbamoyl disulfides)Journal of Polymer Science: Polymer Chemistry Edition, 1973
- Sulfur-Containing Polymers. I. Polycondensation of Chlorocarbonylsulfenyl Chloride with DiaminesMacromolecules, 1972
- Synthesis and Reaction of Polyethylenimine Containing Dithiocarbamoyl GroupThe Journal of the Society of Chemical Industry, Japan, 1966
- Synthesis and Reaction of Polyvinyl Chloride Containing Dithiocarbamate GroupThe Journal of the Society of Chemical Industry, Japan, 1966
- The Reaction of Alkyl Halides with Potassium Thiocyanate'in N, N-DimethylformamideThe Journal of the Society of Chemical Industry, Japan, 1965
- Interaction between Alkyl Halides and Dipolar Aprotic SolventsThe Journal of the Society of Chemical Industry, Japan, 1965
- The Photolysis of Dithiocarbamates and their Catalytic Effects on PhotopolymerizationThe Journal of the Society of Chemical Industry, Japan, 1964
- Physical properties of organic thiones. Part I. Electronic absorption spectra of nitrogen‐containing thione compoundsRecueil des Travaux Chimiques des Pays-Bas, 1960
- Organic Disulfides as Initiators of Polymerization. Part II1Journal of the American Chemical Society, 1958