Synthesis of β-Mono-, Tetra-, and Octasubstituted Sterically Bulky Porphyrins via Suzuki Cross Coupling
- 1 January 1996
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 61 (11) , 3590-3593
- https://doi.org/10.1021/jo952205+
Abstract
β-Mono-, tetra-, and octasubstituted tetramesitylporphyrins were prepared in good yields by Suzuki cross-coupling reactions of β-bromotetramesitylporphyrins with aryl- and alkylboronic acids.Keywords
This publication has 39 references indexed in Scilit:
- Nitrous Oxide Activation by a Ruthenium PorphyrinJournal of the American Chemical Society, 1995
- A Convenient Preparation of Benzyl 4-(R1)-3-(R2)Pyrrole-2-carboxylatesSynthetic Communications, 1995
- Tantalum Porphyrin Chemistry. Synthesis and Reactivity of Organometallic Derivatives and the X-ray Crystal Structure of the Sandwich Compound [Ta(OEP)2][TaCl6]Journal of the American Chemical Society, 1994
- Conformational Effects on the Redox Potentials of Tetraarylporphyrins Halogenated at the β‐Pyrrole PositionsAngewandte Chemie International Edition in English, 1994
- Synthesis of Pyrroles from Benzyl IsocyanoacetateSynthesis, 1994
- Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavageChemical Reviews, 1992
- A ferrochelatase transition-state model. Rapid incorporation of copper(II) into nonplanar dodecaphenylporphyrinInorganic Chemistry, 1992
- .beta.-Halogenated-pyrrole porphyrins. Molecular structures of 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetramesitylporphyrin, nickel(II) 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetramesitylporphyrin, and nickel(II) 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(pentafluorophenyl)porphyrinInorganic Chemistry, 1992
- Perchlorinated and Highly Chlorinated meso‐TetraphenylporphyrinsAngewandte Chemie International Edition in English, 1990
- Preparation and Characterization of a Dialkoxyiron(IV) PorphyrinJournal of the American Chemical Society, 1985