Intermolecular Forces in Globular Molecules. V. Transport Collision Integrals
- 1 February 1968
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 48 (3) , 997-1005
- https://doi.org/10.1063/1.1668857
Abstract
Collision integrals are tabulated for the spherical shell potential over a range of reduced temperatures from 0.2 to 10.0, for a range of core sizes from 1.20 to 4.0 The results are compared with those obtained for other bireciprocal potential models and the Kihara core model. Potential parameters are deduced from gas viscosity data and compared with those obtained from second virial data alone. The viscosities agree for most models over a rather wide temperature range; however, the thermal‐diffusion factors show marked differences especially at low and at high temperatures.Keywords
This publication has 22 references indexed in Scilit:
- Intermolecular Forces in Globular Molecules. IV. Additive Third Virial Coefficients and Quadrupolar CorrectionsThe Journal of Chemical Physics, 1967
- Intermolecular Forces in Globular Molecules. III. A Comparison of the Spherical Shell and Kihara ModelsPhysics of Fluids, 1967
- Nonadditivity of Intermolecular Forces: Effects on the Third Virial CoefficientThe Journal of Chemical Physics, 1966
- Intermolecular Three-Body Forces and Third Virial CoefficientsPhysical Review B, 1966
- Convex Molecules in Gaseous and Crystalline StatesAdvances in Chemical Physics, 1963
- The viscosity of some fluorocarbons in the vapour phaseTransactions of the Faraday Society, 1960
- Intermolecular forces in quasi-spherical molecules. Part 2Transactions of the Faraday Society, 1959
- Virial Coefficients and Models of Molecules in Gases. BReviews of Modern Physics, 1955
- The behaviour of fluids of Quasi-Spherical molecules. I. Gases at low densitiesAustralian Journal of Chemistry, 1954
- Virial Coefficients and Models of Molecules in GasesReviews of Modern Physics, 1953