Conversion of atmospheric dioxygen to a µ–η2,η2-peroxo bridge in a dinuclear uranium(VI) complex
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 1170-1172
- https://doi.org/10.1039/c39930001170
Abstract
N, N-Ethylenebis(2-pyrrolidone)(ebpyrr) reacts with uranyl nitrate in acetonitrile, methanol, or nitromethane to form a helical chain polymer [UO2(NO3)2(ebpyrr)]n and, on exposure to air, also a dinuclear µ-η2, η2-peroxo-bridged complex {[(UO2)(NO3)(ebpyrr)]2(µ-O2)}.Keywords
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