Chemistry of Reactive Organometallic Compounds at Low Temperatures and High Pressures: Reactions of M(CO)6(M = Cr, Mo, W), (η6-C6H3Me3)M(CO)3(M = Cr and Mo), and W(CO)5CS with H2and N2in Polyethylene Matrices
- 1 June 1998
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 17 (13) , 2730-2737
- https://doi.org/10.1021/om970474f
Abstract
No abstract availableKeywords
This publication has 27 references indexed in Scilit:
- Energetics of the Reactions of (η6-C6H6)Cr(CO)3 with n-Heptane, N2, and H2 Studied by High-Pressure Photoacoustic CalorimetryThe Journal of Physical Chemistry, 1996
- Photochemical Generation of Polymer-Bound CpMn(CO)2(.eta.2-C:C) Complexes in Polyethylene Film: A Diagnostic Probe for Investigating the Unsaturation of the PolymerJournal of the American Chemical Society, 1994
- Infrared spectroscopic study of the photochemical substitution and oxidative addition reactions of (.eta.5-C5R5)M(CO)4 compounds of group 5 metals: characterization of the products of reaction with nitrogen, hydrogen and HSiEt3-xClx and the kinetic investigation of (.eta.5-C5R5)M(CO)3 intermediatesJournal of the American Chemical Society, 1993
- Motion of sorbed gases in polymersChemical Society Reviews, 1993
- Organometallic chemistry in supercritical fluids. The generation and detection of dinitrogen and nonclassical dihydrogen complexes of Group 6, 7, and 8 transition metals at room temperatureJournal of the American Chemical Society, 1990
- Supercritical fluids in organometallic chemistry: IR evidence for the photochemical C–H activation of high density polyethylene by [(η5-C5Me5)Ir(CO)2]Journal of the Chemical Society, Chemical Communications, 1990
- Coordination of molecular hydrogen and nitrogen to coordinatively unsaturated tungsten carbonyls in the gas phaseThe Journal of Physical Chemistry, 1989
- The synthesis and spectroscopic identification of [(η5-C5H5)Re(N2)3] and [(η5-C5H5)Re(CO)(N2)2] in supercritical xenon at room temperature and in N2matrices at 20 KJournal of the Chemical Society, Chemical Communications, 1989
- Characterization by infrared and Raman spectroscopy of matrix-isolated M(CO)5N2 (M = chromium, molybdenum, or tungsten) produced by photolysis of M(CO)6Inorganic Chemistry, 1978
- Photochemistry and photoisomerization of five- and six-coordinate d6 transition metal thiocarbonyl complexes in low-temperature matrixesInorganic Chemistry, 1976