Synthesis of a Bis(pyridyl)-Substituted Perylene Diimide Ligand and Incorporation into a Supramolecular Rhomboid and Rectangle via Coordination Driven Self-Assembly
- 31 December 2004
- journal article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 70 (3) , 797-801
- https://doi.org/10.1021/jo048239b
Abstract
The synthesis of a bis(pyridyl)-substituted perylene diimide ligand and its incorporation into a supramolecular rhomboid and rectangle via platinum-mediated self-assembly is reported. Both ensembles are characterized by multinuclear NMR and electrospray ionization mass spectrometry. In addition, the UV/vis spectra of the ensembles exhibit displaced and enhanced absorptions relative to the starting ligand. Size estimations using MM2 simulations show the assemblies are almost 46 A in length.Keywords
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