Gallium-Mediated Highly Regioselective Reaction of Allyl-Type Bromide and Propargyl-Type Bromide With Aldehyde
- 1 April 1999
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 29 (8) , 1287-1296
- https://doi.org/10.1080/00397919908086104
Abstract
In the presence of potassium iodide and lithium chloride, the one-pot reaction of gallium powder, allyl-type bromide and aldehyde shows very high selectivity favoring a-adducts. Under the same condition, the reaction of propargylic bromide with aldehyde exhibit high acetylenic selectivity.Keywords
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