Mild Oxidation of Alcohols with o-Iodoxybenzoic Acid (IBX) in Water/Acetone Mixture in the Presence of β-Cyclodextrin
- 12 February 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 68 (5) , 2058-2059
- https://doi.org/10.1021/jo026751w
Abstract
A mild and efficient oxidation of alcohols with o-iodoxybenzoic acid (IBX) catalyzed by β-cyclodextrin in a water/acetone mixture (86:14) has been developed. A series of alcohols were oxidized at room temperature in excellent yields.Keywords
This publication has 16 references indexed in Scilit:
- A Simple and Advantageous Protocol for the Oxidation of Alcohols with o-Iodoxybenzoic Acid (IBX)Organic Letters, 2002
- Synthesis and oxidation reactions of a user- and eco-friendly hypervalent iodine reagentTetrahedron Letters, 2002
- An Efficient Biomimetic Cleavage of Aziridines with Nucleophiles Catalyzed by β-Cyclodextrin in WaterChemistry Letters, 2001
- Selective deprotection of tetrahydropyranyl ethers catalysed by β-cyclodextrin in waterNew Journal of Chemistry, 2001
- Asymmetric synthesis of 2-azido-1-arylethanols from azido aryl ketone–β-cyclodextrin complexes and sodium borohydride in waterChemical Communications, 2001
- Dynamic kinetic asymmetric synthesis of β-aminoalcohols from racemic epoxides in cyclodextrin complexes under solid state conditionsChemical Communications, 2000
- A User-Friendly Entry to 2-Iodoxybenzoic Acid (IBX)The Journal of Organic Chemistry, 1999
- A mild oxidizing reagent for alcohols and 1,2-diols: o-Iodoxybenzoic acid (IBX) in DMSOTetrahedron Letters, 1994
- One-Pot Two-Steps Synthesis of 1,2-DiolSynthetic Communications, 1989
- Direct α-hydroxylation of ketones using iodosobenzeneTetrahedron Letters, 1981