Hydrogen Bonding between Phenols and Nitriles
- 1 October 1977
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 50 (10) , 2602-2605
- https://doi.org/10.1246/bcsj.50.2602
Abstract
Hydrogen bonding between a number of para-substituted phenols and nitriles was studied by means of infrared spectroscopy using a longer cell. Thermodynamic quantities were determined and found to be the functions of the electronegativity and inductive effect of the phenol and nitrile substituents respectively except for the complexes of t-butyl cyanide for which the −ΔH values were lower than expected. Some correlations among thermodynamic quantities were also established. Both the sample and the reference cells were heated simultaneously by means of a special heating arrangement which minimized the base line errors and made the intensity measurements more accurate.Keywords
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