Hydrogenolysis of CF bonds in fluorinated aromatic hydrocarbons catalysed by nickel complexes
- 1 January 2000
- journal article
- Published by OOO Zhurnal "Mendeleevskie Soobshcheniya" in Mendeleev Communications
- Vol. 10 (2) , 60-61
- https://doi.org/10.1070/mc2000v010n02abeh001171
Abstract
Reactions of hexafluorobenzene, pentafluorobenzene, octafluoronaphthalene and pentafluoropyridine with the NiCl 2 –2,2 ’ -bipyridine (or 1,10-phenanthroline)–Zn reductive catalytic system in DMF (or DMA) in the presence of water or ammonium chloride resulted in the products of C–F bond hydrogenolysis.Keywords
This publication has 11 references indexed in Scilit:
- Reductive defluorination of perfluoroarenes by zinc in aqueous ammoniaJournal of Fluorine Chemistry, 1998
- Polyhalogenated heterocyclic compounds. Part 42.1 Fluorinated nitrogen heterocycles with unusual substitution patternsJournal of the Chemical Society, Perkin Transactions 1, 1998
- Rapid Intermolecular Carbon−Fluorine Bond Activation of Pentafluoropyridine at Nickel(0): Comparative Reactivity of Fluorinated Arene and Fluorinated Pyridine DerivativesOrganometallics, 1997
- Recent Advances in C–F Bond ActivationEuropean Journal of Inorganic Chemistry, 1997
- Group IV Metallocene-Mediated Synthesis of Fluoroaromatics via Selective Defluorination of Saturated PerfluorocarbonsJournal of the American Chemical Society, 1996
- Selective room temperature hydrogenolysis of aromatic fluorocarbons mediated by a low-valent zirconium complexChemical Communications, 1996
- Homogeneous rhodium complex-catalyzed hydrogenolysis of C-F bonds.Journal of the American Chemical Society, 1995
- Catalytic Activation of Carbon-Fluorine Bonds by a Soluble Transition Metal ComplexScience, 1994
- Activation of Carbon-Fluorine Bonds by Metal ComplexesChemical Reviews, 1994
- Regiospecific replacement of fluorine by hydrogen in an aromatic ring induced by a rare earth organometallicTetrahedron Letters, 1994