A Tris(μ-hydroxy)tricopper(II) Complex as a Model of the Native Intermediate in Laccase and Its Relationship to a Binuclear Analogue
- 8 March 2005
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 44 (7) , 2131-2133
- https://doi.org/10.1021/ic048182b
Abstract
The reaction of a copper(I) complex with a sterically demanding secondary diamine ligand and O2 yields a tris(μ-hydroxy)tricopper(II) complex. This complex is a structural model of the proposed native intermediate in multicopper oxidases, with interesting structural, magnetic, and solution properties.Keywords
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