PREPARATION AND ELECTROCHEMICAL PROPERTIES OF A NEW ORGANIC DONOR BIS-(HYDROXYMETHYLETHYLENEDITHIO)-TETRATHIAFULV ALENE
- 1 August 1997
- journal article
- research article
- Published by Taylor & Francis in Phosphorus, Sulfur, and Silicon and the Related Elements
- Vol. 127 (1) , 81-89
- https://doi.org/10.1080/10426509708040498
Abstract
Preparation and characterization of a new organic donor molecule bis(hydroxymethylethylenedithio)-tetrathiafulvalene is reported. Cyclic voltammogram (Figure 1) of the donor molecule shows two reversible redox processes in n-Bu4NBF4/DMF system at half-wave potentials of 0.64 and 0.81 V vs SCE, respectively, which are higher than those of the well-known organic donor molecule bis(ethylenedithio)-tetrathiafulvalene with the corresponding values of 0.60 and 0.73 V, respectively. In addition, the π-donor ability of some related donor molecules of the same series is compared and the effects of solvents on the half-wave potentials of the donors are studied.Keywords
This publication has 7 references indexed in Scilit:
- X-ray photoelectron spectra and electrical properties of new metal complexes of [M(DMID)2][TAA]xSynthetic Metals, 1995
- STUDY ON THE SYNTHESIS OF THE ELECTRON DONOR MOLECULE OF [BIS(ETHYLENEDITHIO)-TETRATHIAFULVALENE] (BEDT-TTF)Phosphorus, Sulfur, and Silicon and the Related Elements, 1995
- A construction principle of the κ‐phase based on the efficient (O-H)donor…Oanion structural functionality: The examples of κ‐(EDT–TTF(CH2OH))2X (X = ClO and ReO)Advanced Materials, 1992
- New vinylogous tetrathiafulvalene (TTF) π-electron donorsTetrahedron Letters, 1992
- Thion‐ und Dithioester, XXIV. Synthese von TetrathiooxalesternEuropean Journal of Inorganic Chemistry, 1980
- 1.3-DITHIOL-2-THION-4.5-DITHIOLAT AUS SCHWEFELKOHLENSTOFF UND ALKALIMETALLPhosphorus and Sulfur and the Related Elements, 1979
- ‘Organic metals’: alkylthio substitution effects in tetrathiafulvalene–tetracyanoquinodimethane charge-transfer complexesJournal of the Chemical Society, Chemical Communications, 1978