Differential scattering of spin±1/2 polarized neutrons by chiral systems. III. Coupled oscillator model
- 15 August 1980
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 73 (4) , 1591-1600
- https://doi.org/10.1063/1.440339
Abstract
The general theory of polarized neutron scattering by nonmagnetic chiral systems (see Ref. 1) is applied to a specific model system comprised of vibrating nuclei. The model scattering system is made up of two ’’spinless’’ nuclei constrained by external (crystal or molecular) force fields to vibrate as linear (harmonic) oscillators along mutually orthogonal, laboratory-fixed directions. Interactions between the two vibrating nuclei are introduced so that the dynamics of the two linear oscillators are coupled. This coupled oscillator system is constructed to reflect the chirality of the local force fields in the scattering medium. The vibrational states of the chiral coupled oscillator system lack parity, and it is shown that left-handed and right-handed polarized neutrons are scattered differentially by vibrational excitations (and de-excitations) within the system. Calculations are performed to estimate the magnitude of this differential polarized neutron scattering, and the detectability of this phenomenon is assessed.Keywords
This publication has 11 references indexed in Scilit:
- "Optical activity" in the scattering of neutrons from chiral moleculesPhysical Review A, 1979
- Neutron optical activityThe Journal of Chemical Physics, 1979
- Differential scattering of spin ± (1/2) polarized neutrons by chiral systems. II. Condon oscillator modelThe Journal of Chemical Physics, 1977
- Differential scattering of spin ± (1/2) polarized neutrons by chiral systems. I. TheoryThe Journal of Chemical Physics, 1977
- Neutron Optical Activity Through Spin–Orbit InteractionCanadian Journal of Physics, 1975
- Optical activity for neutronsPhysical Review D, 1974
- Vibrational optical activityThe Journal of Chemical Physics, 1973
- On the Polarization of Fast NeutronsPhysical Review B, 1948
- Theories of Optical Rotatory PowerReviews of Modern Physics, 1937
- One-Electron Rotatory PowerThe Journal of Chemical Physics, 1937