A NEW ASYMMETRIC SYNTHESIS OF CHIRALt-BUTYLt-BUTANETHIOSULPHINATE1
- 1 August 1983
- journal article
- research article
- Published by Taylor & Francis in Phosphorus and Sulfur and the Related Elements
- Vol. 16 (3) , 267-270
- https://doi.org/10.1080/03086648308080478
Abstract
Thermal decomposition of di-t-butyl sulphoxide (3) in the presence of chiral amines has been found to give chiral t-butyl t-butanethiosulphinate (1). Optical purities of 1 were in the range between 1 and 26%.Keywords
This publication has 8 references indexed in Scilit:
- Chemistry of oxaziridines. 3. Asymmetric oxidation of organosulfur compounds using chiral 2-sulfonyloxaziridinesJournal of the American Chemical Society, 1982
- Organosulfur compounds. 30. Improved procedure for synthesis of chiral sulfoxidesThe Journal of Organic Chemistry, 1982
- Chiral Organosulfur CompoundsTopics in Stereochemistry, 1982
- Aktuelle Ergebnisse zur Synthese und Reaktivität der Sulfinsäuren und ihrer DerivateZeitschrift für Chemie, 1980
- Organosulfur compounds. 13. Optical resolution of chiral sulfinyl compounds via .beta.-cyclodextrin inclusion complexesJournal of the American Chemical Society, 1978
- Optically stable thiosulphinate S-esters: asymmetric synthesis and nucleophilic substitution at sulphinyl sulphurJournal of the Chemical Society, Chemical Communications, 1976
- Chemistry of alkyl thiosulfinate esters. VI. Preparation and spectral studiesJournal of the American Chemical Society, 1974
- t-Butylsulfenic AcidJournal of the American Chemical Society, 1967