Hypernetted chain solutions for the classical one-component plasma up to Γ=7000
- 1 October 1974
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 61 (7) , 2680-2689
- https://doi.org/10.1063/1.1682399
Abstract
The hypernetted chain equation has been solved numerically for the classical one‐component plasma in a uniform background up to Γ=7000, where Γ=(Ze)2/kTa and a is the ion‐sphere radius. Numerical results are presented. The distribution functions and thermodynamical quantities obtained are in good agreement with the Monte Carlo results in the fluid region. The average potential energy Ū/NkT is in error by less than 0.8% for 20≤Γ≤160 and approaches −0.8995Γ as Γ approaches infinity. The pressure and the free energy calculated do not show any evidence of a phase transition. However, the distribution function g(r) for has an unusual behavior between 2.5<r<4.0, resembling somewhat that of a hcp crystal. If we assume the sum of the bridge diagram to be of the form B(r)=−λΓ/r where λ=0.6 erf (0.024Γ), the distribution function calculated agrees to within about ±0.02 with the Monte Carlo g(r) in the whole fluid region.
Keywords
This publication has 21 references indexed in Scilit:
- Statistical Mechanics of Dense Ionized Matter. II. Equilibrium Properties and Melting Transition of the Crystallized One-Component PlasmaPhysical Review A, 1973
- Statistical Mechanics of Dense Ionized Matter. I. Equilibrium Properties of the Classical One-Component PlasmaPhysical Review A, 1973
- Modified Hypernetted-Chain Equation for the Screened Coulomb PotentialPhysical Review A, 1973
- Numerical fourier transforms in one, two, and three dimensions for liquid state calculationsJournal of Computational Physics, 1971
- Computer "Experiments" on Classical Fluids. II. Equilibrium Correlation FunctionsPhysical Review B, 1968
- Exact Solution of the Percus-Yevick Integral Equation for Hard SpheresPhysical Review Letters, 1963
- Integral Equation for Pair Distribution FunctionProgress of Theoretical Physics, 1960
- New method for the calculation of the pair correlation function. IPhysica, 1959
- Analysis of Classical Statistical Mechanics by Means of Collective CoordinatesPhysical Review B, 1958
- Radial Distribution Functions and the Equation of State of a Fluid Composed of Rigid Spherical MoleculesThe Journal of Chemical Physics, 1950