Synthesis and Some Properties of a New Fluoroperoxo Complex of Vanadium(V)
- 1 January 1982
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 12 (4) , 455-461
- https://doi.org/10.1080/00945718208063128
Abstract
A new solid fluoroperoxo complex of vanadium(V) has been synthesised under high acidity conditions, starting from vanadium pentoxide, hydrofluoric acid and hydrogen peroxide. The dried solid has potassium, vanadium, peroxide and fluorine in the molar ratio 1.1:1.0:1.0:1.0. The infrared and laser Raman spectra show characteristic absorption bands due to the vanadyl moiety and the bridged V-O-V species.Keywords
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