Commensurate-incommensurate transition of solid krypton monolayers on graphite

Abstract
Low-energy electron-diffraction (LEED) data for the commensurate-incommensurate transition in solid krypton monolayers on graphite are reanalyzed and compared to recent x-ray diffraction data. For the temperature range 52 to 89 K, the mean misfit versus chemical potential change for both sets of data can be expressed as a power law with an exponent of about 13. The critical pressure at which the transition occurs is consistent with Pc(T)=(4.5×10+9Torr) exp(1990KT) for 52<T<123 K. Analysis of the LEED photographs at 52 K indicates that the krypton monolayer starts to rotate in an apparently second-order transition when the mean misfit exceeds two percent.

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