Proof of a Reversible, Pairwise Hydrogen Transfer during the Homogeneously Rhodium(I)‐Catalyzed Hydrogenation of α,β‐Unsaturated Carbonic Acid Derivatives with In Situ NMR Spectroscopy and Parahydrogen
- 18 November 1996
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 35 (21) , 2505-2507
- https://doi.org/10.1002/anie.199625051
Abstract
No abstract availableKeywords
This publication has 12 references indexed in Scilit:
- Isotopic Enrichment by Asymmetric Deuteriation. An Investigation of the Synthesis of Deuteriated (S)-(−)-Methylsuccinic Acids from Itaconic AcidJournal of the American Chemical Society, 1996
- Structure and dynamics of intermediates in asymmetric hydrogenation by rhodium complexes of (2-methoxyphenyl)-P-phenyl-P-(2′-diphenylphosphino)ethylphosphineJournal of the Chemical Society, Chemical Communications, 1995
- Catalyst–substrate complexes of chiral seven-membered ring chelates of rhodium(I)-bis(phosphinites)Journal of the Chemical Society, Chemical Communications, 1995
- In Situ NMR Investigations of Photocatalyzed Hydrogenations with Parahydrogen in the Presence of Metal Carbonyl Compounds of Group 6Angewandte Chemie International Edition in English, 1994
- In‐situ‐NMR‐Untersuchungen photokatalysierter Hydrierungen mit Parawasserstoff in Gegenwart von Carbonylmetallverbindungen der 6. GruppeAngewandte Chemie, 1994
- Asymmetric catalysis. 80. Mechanistic aspects of the rhodium-catalyzed enantioselective transfer hydrogenation of .alpha.,.beta.-unsaturated carboxylic acids using formic acid/triethylamine (5:2) as the hydrogen sourceJournal of the American Chemical Society, 1993
- Carbohydrate phosphinites as chiral ligands for asymmetric synthesis catalyzed by complexes: V. New rhodium(I)-chelates prepared by precipitation from the equilibrium between neutral and cationic complexes and hydrolysis of their bonded ligandsJournal of Organometallic Chemistry, 1989
- Para hydrogen induced polarization in hydrogenation reactions catalyzed by ruthenium phosphine complexesJournal of the American Chemical Society, 1988
- Parahydrogen and synthesis allow dramatically enhanced nuclear alignmentJournal of the American Chemical Society, 1987
- Transformation of Symmetrization Order to Nuclear-Spin Magnetization by Chemical Reaction and Nuclear Magnetic ResonancePhysical Review Letters, 1986