Variation of enantiomeric composition of ?-pinene in norway spruce,Picea abies, and its influence on production of verbenol isomers byIps typographus in the field
- 1 February 1989
- journal article
- research article
- Published by Springer Nature in Journal of Chemical Ecology
- Vol. 15 (2) , 541-548
- https://doi.org/10.1007/bf01014699
Abstract
The enantiomeric composition of α-pinene in individual Norway spruce trees [Picea abies (L.) Karst.] was determined on a chiral GC column after stereoselective hydroboration-oxidation followed by a reaction with isopropyl isocyanate to form the carbamate derivative. The enantiomeric composition varied considerably between trees of different genetic origin. There was a strong correlation between the chirality of α-pinene in host spruce trees and thecis/trans ratio of verbenols found in the hindguts of the bark beetleIps typographus (L.) infesting the trees.Keywords
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