Ditopic Ligands. The Synthesis of a Series of Phosphine‐Functionalised Macrocycles
- 7 May 1986
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 69 (3) , 580-586
- https://doi.org/10.1002/hlca.19860690307
Abstract
The synthesis of a series of phosphine‐functionalised macrocycles, 1–6, is described. The combination of N‐and O‐sites with P‐ and S‐sites provides ligands which may bind transition or non‐transition metal ions; as a consequence, they give access to dinuclear complexes containing both a Lewis acid and a redox metallic site. Compounds 1,2 and 6 are heterodinucleating ligands capable of binding two dissimilar metals in proximity. Macrocycles 3–5 are homotopic ligands which may form homodinuclear complexes of transition metals.Keywords
This publication has 16 references indexed in Scilit:
- Ditopic ligands. Synthesis and complexation properties of a pyridine-containing macrocyclic hexa-amine, ‘pyridine[24]N6O2’Journal of the Chemical Society, Chemical Communications, 1985
- Transition metal complexes with bidentate ligands spanningtrans-positions. Part XIV. Some complexes of 2,11-bis(diphenylphosphinomethyl)benzo[c]phenanthrene with platinum (0) and their reactivitiesHelvetica Chimica Acta, 1984
- Phosphine functionalized macrocycles. A new type of bridging ligand for the synthesis of heterometallic complexesJournal of the American Chemical Society, 1982
- Synthetic approaches to coordinatively unsaturated heterobimetallic complexesJournal of the American Chemical Society, 1982
- Synthesis and structure of trans-[[[cis-tetracarbonylbis(N-((2-diphenylphosphinamido)ethyl)salicylaldimino-P)]molybdenum(0)]-N,N1,O,O1]nickel(II), a novel bimetal trans-ligating tetradentate Schiff base complex with a "fly-over" chain containing a metal atomJournal of the American Chemical Society, 1981
- Synthetic, structural, stereochemical, and catalytic studies on carbonyliridium(I) complexes of o-(diphenylphosphino)-N,N-dimethylaniline, o-(diphenylphosphino)-N,N-dimethylbenzylamine, 2-(diphenylphosphino)-N,N-dimethylethylamine, and 3-(diphenylphosphino)-N,N-dimethylpropylamineInorganic Chemistry, 1980
- 4,10-Bis(2-hydroxyethyl)-1,7-dioxa-4,10-diazacyclododecane. A Strong Calcium-binding Ligand.Acta Chemica Scandinavica, 1979
- Binuclear macrocyclic copper(II) complexes as receptors for small bridging ligands: X-ray crystal and molecular structure of a µ-azido complexJournal of the Chemical Society, Chemical Communications, 1979
- Synthesis oftrans-4,5-Bis[diphenylarsinomethyl]-2,2-dimethyl-1,3-dioxolan and an Improved Preparation of its Phosphine Analogue (DIOP)Synthesis, 1979
- Transition‐Metal Complexes with Bidentate Ligands Spanning trans‐Positions. II. Preparation and properties of complexes trans‐[MX2(1)] (M = Ni, Pd and Pt; X = Cl, Br and I; 1 = 2, 11‐Bis(diphenylphosphinomethyl)benzo[c]phenanthrene)Helvetica Chimica Acta, 1976