A New Look at Boron Enolate Chemistry: Aminative C−C Bond Formation Using Diaminoboron Enolate with Aldehyde
- 9 March 2004
- journal article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 6 (7) , 1167-1169
- https://doi.org/10.1021/ol0497436
Abstract
Unlike ordinary boron enolates, such as dialkylboryl (R2B) and dialkoxyboryl ((RO)2B) derivatives, reactions of diaminoboryl ((R2N)2B) enolates with aldehydes proceed with the concurrent transfer of amino and enoxy groups from the boron to the aldehyde carbon, yielding β-amino ketones in a selective manner.Keywords
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