Analysis of the far infrared H2–He spectrum

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Abstract
Previous measurements of the far infrared absorption due to H2–He collisions at the temperatures of 77, 195, and 292 K are analyzed. The spectra are fitted by a semiempiricalline shape representing the isotropic induced overlap component and combined anisotropic quadrupolar and overlap components. The experimental spectral moments are evaluated and compared with theory for several induced‐dipole and potential models. From the isotropic contribution, the range and strength of the induced dipole is evaluated and compared with the results of ab initio calculations. Fitting parameters are obtained with physically plausible temperature dependences which allow simple and accurate representation of the spectra and of their moments at temperatures different from those of the measurements.