A quantitative analysis of the inelastic electron tunnelling spectrum of the formate ion
- 23 November 1986
- journal article
- Published by IOP Publishing in Journal of Physics C: Solid State Physics
- Vol. 19 (33) , 6645-6654
- https://doi.org/10.1088/0022-3719/19/33/013
Abstract
The authors present the results of a detailed quantitative analysis of mode intensities in inelastic electron tunnelling spectra of the formate ion. They find that the theoretical approach of Phillips and Adkins (1985) can account successfully for the intensities of those spectral components that can be evaluated unambiguously from experimental spectra. They conclude that useful information can be obtained from quantitative aspects of inelastic electron tunnelling spectra, even in cases where the complexity is such that any attempt at full analysis would not be feasible.Keywords
This publication has 21 references indexed in Scilit:
- Study of the orientation of thiourea adsorbed on aluminum oxide by tunneling spectroscopy. II. Comparison of experimental and calculated intensitiesPhysical Review B, 1985
- Inelastic electron tunnelling spectroscopyJournal of Physics C: Solid State Physics, 1985
- An iras study of formic acid and surface formate adsorbed on Cu(110)Surface Science, 1983
- Orientation of chemisorbed species from electron impact and dipole selection rules: The formate ion on Pt{110}Surface Science, 1983
- Experimental study of relative intensities in inelastic electron-tunneling spectraPhysical Review B, 1982
- Formate anion: The physical force fieldJournal of Molecular Spectroscopy, 1981
- Acetates and acetato-complexes. Part 2. Spectroscopic studiesJ. Chem. Soc., Dalton Trans., 1976
- Application of minicomputers in high resolution electron tunnelingReview of Scientific Instruments, 1975
- The fundamental vibrational spectra of the formates of the main group elementsSpectrochimica Acta, 1964
- THE VIBRATIONAL SPECTRA OF THE FORMATE, ACETATE, AND OXALATE IONSCanadian Journal of Chemistry, 1956