ENDOR investigation of electron spin transfer in (CrF6)3-
- 28 April 1977
- journal article
- Published by IOP Publishing in Journal of Physics C: Solid State Physics
- Vol. 10 (8) , L201-L203
- https://doi.org/10.1088/0022-3719/10/8/009
Abstract
ENDOR measurements have been made on the linear bond structure Cr3+-F--Cd2+ in crystals of CsCdF3:Cr3+. The observed hyperfine interactions with the 19F, 111Cd and 113Cd nuclei indicate that the unpaired spin fractions in 2psigma and 2ppi orbitals on the F- ion are fsigma =-0.1% and fpi =4.3%. The value of fsigma , about which there has been some uncertainty in the literature, is considerably smaller than recent estimates.Keywords
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