Sol–gel synthesis of the magnetically frustrated oxides Sr2FeSbO6and SrLaFeSnO6
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 5 (1) , 75-78
- https://doi.org/10.1039/jm9950500075
Abstract
The use of the sol–gel synthesis method has been extended to include the preparation of stannates and antimonates from a citrate precursor. Samples of SrLaFeSnO6 and Sr2FeSbO6 have been prepared in a few hours. The structural and magnetic properties of the former are compared with those of a sample prepared over a period of several days by a solid-state route. The properties of Sr2FeSbO6 have been investigated by a combination of X-ray diffraction Mössbauer spectroscopy and SQUID magnetometry. The monoclinic perovskite structure has a partially (84%) ordered distribution of Fe and Sb cations over the six-coordinate sites; a transition to a magnetically frustrated phase occurs at 36 K.Keywords
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