Hydrotalcite-Catalyzed Alkylation of 2,4-Pentanedione
- 1 June 1995
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 25 (11) , 1745-1750
- https://doi.org/10.1080/00397919508015859
Abstract
A synthetic anionic clay, hydrotalcite (Mg/Al = 2.8), calcined under dry air at 450 [ddot]C, has proved to be an efficient catalyst for the selective C-monoalkylation of 2,4-pentanedione with reactive alkylating reagents.Keywords
This publication has 17 references indexed in Scilit:
- A dual mechanistic pathway in the alkylation of pentane-2,4-dione through its Co(II) complexTetrahedron Letters, 1988
- Alkylation of β-diketones through their co(II), co(III) and zn(II) complexes. 1-Bromoadamantane as alkylating agent.Tetrahedron Letters, 1985
- Reactions of Bis[pentane-2,4-dionato]cobalt(II) with Alkyl HalidesSynthesis, 1979
- Hydrogen bonding in organic synthesis. Part 6. C-Alkylation of β-dicarbonyl compounds using tetra-alkylammonium fluoridesJournal of the Chemical Society, Perkin Transactions 1, 1977
- Mono-C-alkylation of β-dicarbonyl compounds using tetraethylammonium fluorideJournal of the Chemical Society, Chemical Communications, 1977
- Alkylations in neutral media. Reactions of nickel(ii) bis-2,4-pentanedionato with alkyl halidesTetrahedron Letters, 1975
- Formation of 1,1-dimethylallyl derivatives by reaction of 3,3-dimethylallyl halides with copper(II) chelates of acetylacetone and methyl acetoacetateJournal of the Chemical Society, Perkin Transactions 1, 1973
- Alkylation of thallium enolates of .beta.-keto sulfoxides, .beta.-diketones, and .beta.-keto esters. Alternative viewpointThe Journal of Organic Chemistry, 1972
- Reactivity of ambident anionsTetrahedron, 1971
- Notes-Alkylation Reactions in Dimethyl SulfoxideThe Journal of Organic Chemistry, 1961