Growth of Bulk CuGaS2 Single Crystals Using Solution Bridgman Method

Abstract
Bulk CuGaS2 single crystals have been grown using a modified Bridgman technique from In solutions (solution Bridgman method). At temperatures below 1020°C, where a miscibility gap exists in the In solutions with a stoichiometric CuGaS2 solute, sulfur-excess In solutions are required for obtaining single crystals. The crystals are generally CuGa x In1-x S2 alloys with (1-x)=0.03–0.06 due to partial occupation of Ga sites by In atoms.

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