Bounds, Successive Approximations, and Thermodynamic Limits for Distribution Functions, and the Question of Phase Transitions for Classical Systems with Non-negative Interactions
- 20 July 1970
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 25 (3) , 152-155
- https://doi.org/10.1103/physrevlett.25.152
Abstract
It is shown rigorously that, for systems with non-negative interactions and integrable Mayer bonds (e.g., hard spheres), distribution functions and the thermodynamic ratio exist in the limit , and are analytic functions of the activity , for in the right-hand half-plane, with the absolute value of the integral of the bond. Heuristic arguments then indicate that these functions are continuous in for all . This would mean that no Ehrenfest phase transitions are possible for such systems.
Keywords
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