Dialkylammonium‐Ionen/Kronenether‐Komplexe: Vorläufer einer neuen Familie „mechanisch”︁ verknüpfter Moleküle
- 1 September 1995
- journal article
- zuschrift
- Published by Wiley in Angewandte Chemie
- Vol. 107 (17) , 1997-2001
- https://doi.org/10.1002/ange.19951071711
Abstract
Eine einfache Form der molekularen Erkennung – die Bindung von disubstituierten Ammoniumsalzen wie Dibenzyl‐ und Di‐n‐butylammonium‐hexafluorophosphat an Kronenether wie Dibenzo‐[24]Krone‐8 – führt zu den 1:1‐Komplexen 1. Die supramolekularen Strukturen dieser Komplexe werden durch Wasserstoffbrückenbindungen, elektrostatische Pol‐Dipol‐Wechselwirkungen und dispersive Wechselwirkungen stabilisiert. magnified imageKeywords
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