The total synthesis of some deuterium labelled pentaketide derivatives of orsellinic acid
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 6,p. 1685-1689
- https://doi.org/10.1039/p19810001685
Abstract
The total syntheses of 4,6-dihydroxy-3,5-dimethyl-2-(1-methyl-2-oxopropyl)benzaldehyde and 6,8-dihydroxy-3,4,5,7-tetramethyl-3,4-dihydroisocoumarin, which allow the insertion of specific deuterium labels, are described.Keywords
This publication has 3 references indexed in Scilit:
- The synthesis of indan-1-ones and isocoumarinsJournal of the Chemical Society, Perkin Transactions 1, 1981
- New insights into polyketide metabolism; the use of protium as a tracer in the biosynthesis of citrinin by Penicillium citrinumJournal of the Chemical Society, Perkin Transactions 1, 1980
- Biosynthesis of citrinin in Penicillium citrinum: advanced precursor studies using 2H nuclear magnetic resonance spectroscopyJournal of the Chemical Society, Chemical Communications, 1980