c-axis electrical resistivity of SbCl5-graphites
- 15 February 1983
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 27 (4) , 2477-2479
- https://doi.org/10.1103/physrevb.27.2477
Abstract
-axis electrical resistivity was measured from 1.5 to 300 K on the acceptor-type Sb-graphite intercalation compounds of stages 1-6 and 10. The resistivity of the compounds is up to an order of magnitude larger (- Ω m) than that of the parent highly-oriented pyrolytic graphite material, indicating that the mean free path is comparable to an atomic spacing. In spite of this large resistivity an entirely metallic temperature dependence of resistivity is observed for stages 1-3. Higher-stage compounds show metallic character only at high temperatures; as the temperature decreases one observes a crossover to an activated dependence of the resistivity. A model, based on defect-mediated short-circuiting channels, is proposed in order to reconcile the metallic dependence with the large -axis resistivities observed in these compounds.
Keywords
This publication has 8 references indexed in Scilit:
- Unusual temperature dependence of the resistivity of exfoliated graphitesPhysical Review B, 1983
- Commensurate-incommensurate transitions in Sbintercalated graphitesPhysical Review B, 1982
- Thermal transport properties of SbCl5graphitePhysical Review B, 1982
- The C-axis electrical resistivity of highly oriented pyrolytic graphitePhilosophical Magazine Part B, 1981
- Intercalation compounds of graphiteAdvances in Physics, 1981
- Thermal stability and structure of graphite-antimony pentachloride compoundsCarbon, 1975
- Conduction in non-crystalline systems IX. the minimum metallic conductivityPhilosophical Magazine, 1972
- Electrical anisotropy of synthetic metals based on graphiteProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1972