Flash Photolysis of Hydrogen Peroxide I: The Reaction of Ozonide with Hydrogen Peroxide
- 1 January 1968
- journal article
- research article
- Published by Wiley in Israel Journal of Chemistry
- Vol. 6 (1) , 43-51
- https://doi.org/10.1002/ijch.196800007
Abstract
The photochemistry of basic aqueous solutions containing hydrogen peroxide and oxygen has been investigated by the flash photolysis method. The decay of O3− was followed at 4300 Å over the pH range 13 – 13.7 as a function of hydrogen peroxide and oxygen concentrations. The decay was found to be of the first order under all conditions −[d(O3)−/dt] = kobs[O3−]. The pseudo first‐order rate constant kobs was found to be dependent on H2O2 and O2 concentrations. A mechanism which is consistent with the experimental results is suggested.Keywords
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