The structure and magnetism of a trimetallic µ-oxo ruthenium(IV) porphyrin–iron(III) salicylideneamine complex containing the Fe–O–Ru–O–Fe system
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 971-973
- https://doi.org/10.1039/c39920000971
Abstract
The redox reaction between trans-dioxotetraphenylporphyrinruthenium(VI) and two equivalents of the five-coordinate iron(II) salicylideneamine complex Fe(salmah) in toluene results in the transfer of two electrons and formation of the novel bis-µ-oxo trimetallic complex [RuIV(tpp){OFeIII(salmah)}2] containing first and second row d-blockions which has been characterized by a crystal structure determination and its variable temperature magnetic properties.Keywords
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