Direct Catalytic Enantioselective Reduction of Achiral α,β-Ynones. Strong Remote Steric Effects Across the C−C Triple Bond

This publication has 18 references indexed in Scilit:

• Novel electronic effects of remote substituents on the oxazaborolidine-catalyzed enantioselective reduction of ketones
  Tetrahedron Letters, 1995
• The Triisopropylsilyl Group in Organic Chemistry: Just a Protective Group, or More?
  Chemical Reviews, 1995
• Preparation and molecular structure determination of dialkynyliodonium salts: (RC.tplbond.C)2I+ -OTf
  Journal of the American Chemical Society, 1991
• Selective reductions. 46. Effect of the steric requirement at the 2-position of apopinene on chiral reductions. B-(iso-2-ethylapopinocampheyl)- and B-(iso-2-n-propylapopinocampheyl)-9-borabicyclo[3.3.1]nonanes as improved reagents for the chiral reduction of .alpha.,.beta.-acetylenic ketones and .alpha.-keto esters
  The Journal of Organic Chemistry, 1990
• Catalytic asymmetric synthesis of optically active alkynyl alcohols by enantioselective alkynylation of aldehydes and by enantioselective alkylation of alkynyl aldehydes
  Journal of the Chemical Society, Perkin Transactions 1, 1990
• Amino Alcohol Mediated Enantioselective Addition of 2-Phenylethynylzinc Bromide to Aldehydes
  Synlett, 1990
• [2,3] Wittig rearrangement of nonracemic propargyl ethers leading to allenes of high stereochemical integrity
  The Journal of Organic Chemistry, 1989
• ASYMMETRIC ADDITION OF ACETYLIDE TO ALIPHATIC ALDEHYDES—PREPARATION OF OPTICALLY ACTIVE 5-OCTYL-2(5H)-FURANONE—
  Chemistry Letters, 1980
• ENANTIOSELECTIVE ADDITION OF ACETYLENE TO ALDEHYDE. PREPARATION OF OPTICALLY ACTIVE ALKYNYL ALCOHOLS
  Chemistry Letters, 1979
• Substitutions‐ und Additionsreaktionen an silylierten Acetylenen
  European Journal of Inorganic Chemistry, 1963