Ionization-detected Raman studies of the 1600 cm−1 Fermi dyad of benzene
- 1 October 1985
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 83 (7) , 3311-3317
- https://doi.org/10.1063/1.449190
Abstract
We present the first rotationally resolved Raman spectrum of a degenerate rovibrational transition in benzene as a demonstration of the high spectral resolving power and sensitivity attainable by ionization detected stimulated Raman spectroscopy (IDSRS). The double-resonance form of the technique allows the clean separation of the Raman spectra of the Fermi dyad composed of the ν16 fundamental and ν2+ν18 combination vibrations.Keywords
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