Effects of relativity on multiplet splitting and decay rates of the1s2p2configuration of Li-like ions

Abstract
Properties of the 1s2p2 states of Li-like ions are calculated relativistically for 6Z30, with particular attention to the effects of the Breit interaction on multiplet splitting and the radiationless transitions through which these states decay. The full Breit interaction (magnetic and retardation terms) is included in calculating fine structure. Transition rates are computed in relativistic intermediate coupling with configuration interaction. Both the spin-orbit and magnetic interactions are incorporated in the calculations. Results are compared with earlier calculations and with experiment, and the physics of observed relativistic and configuration-interaction effects is discussed.