On the use of breakdown graphs combined with energy‐dependent mass spectrometry to provide a complete picture of fragmentation processes
- 19 July 2002
- journal article
- research article
- Published by Wiley in Rapid Communications in Mass Spectrometry
- Vol. 16 (16) , 1595-1598
- https://doi.org/10.1002/rcm.758
Abstract
Both breakdown graphs and energy‐dependent (ED) maps provide a means of visually representing the fragmentation processes resulting from collision‐induced dissociation at different energies. The two presentation methods may be combined for a complete picture of the appearance, disappearance and maximum abundance collision potentials of each of the ions involved in the fragmentation process. A demonstration of this approach is presented using two very different classes of compound, an amino acid and a transition metal carbonyl cluster. Copyright © 2002 John Wiley & Sons, Ltd.Keywords
This publication has 30 references indexed in Scilit:
- Tuning compounds for electrospray ionization/in‐source collision‐induced dissociation and mass spectra library searchingJournal of Mass Spectrometry, 2001
- Mass Spectrometric Method for the Rapid Characterization of Transition Metal Carbonyl Cluster Reaction MixturesOrganometallics, 2001
- Electrospray ionisation tandem mass spectrometry in the characterisation of isomeric benzofurocoumarinsRapid Communications in Mass Spectrometry, 2001
- Combining energy‐dependent electrospray ionisation with tandem mass spectrometry for the analysis of inorganic compoundsRapid Communications in Mass Spectrometry, 2001
- Insights into the elimination of HCHO from the clusters [Mn(CO)m(COOMe)]− (Mn = Ru6C, m = 16; Mn = Rh6, m = 15) provided by electrospray mass spectrometry †J. Chem. Soc., Dalton Trans., 2000
- Energy-dependent electrospray ionisation mass spectrometry: applications in transition metal carbonyl chemistryRapid Communications in Mass Spectrometry, 2000
- Collision-Induced Dissociation of Ions within the Orifice−Skimmer Region of an Electrospray Mass SpectrometerAnalytical Chemistry, 2000
- Electrospray Ionization Mass Spectroscopy: Part I. Instrumentation and Spectral InterpretationJournal of Chemical Education, 1996
- Electrospray Ionization for Mass Spectrometry of Large BiomoleculesScience, 1989
- The chemistry of polynuclear compounds. Part XXVI. Products of the pyrolysis of dodecacarbonyl-triangulo-triruthenium and -triosmiumJ. Chem. Soc., Dalton Trans., 1975