Highly diastereoselective addition reactions of a radical derived from a β-ethoxycarbonyl sulphoxide
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1151-1152
- https://doi.org/10.1039/c39910001151
Abstract
The 1-ethoxycarbonyl-1-p-tolylsulphinylethyl radical 2, generated by iodine abstraction from 1, adds to the alkenic bond in allyltriphenylstannane or in hex-1-ene with very high diastereoselectivity (>98%).Keywords
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