Model structural types for rationalising stoichiometries and coordination numbers in lithium amidomagnesiates: syntheses and X-ray diffraction studies of [{Mg(NR2)2}2], [Li2Mg(NR2)4] and [LiMg(NR2)3·py](R = benzyl, py = pyridine)
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 769-770
- https://doi.org/10.1039/c39940000769
Abstract
Factors governing the intermetallic ratios and coordination geometries in lithium amidomagnesiates are discussed with reference to three model crystal structures containing the same (dibenzylamido) ligand, which remarkably reveal that an unsolvated lithium can induce coordination expansion about a magnesium centre.Keywords
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