Diamminebis(1,5‐cyclooctadiene)(μ‐1,4,10,13‐tetraoxa‐7, 16‐diazacyclooctadecane‐N7, N16)dirhodiumbis‐(hexafluorophosphate): An Example of Simultaneous First and Second Sphere Coordination
- 1 February 1985
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 24 (2) , 135-136
- https://doi.org/10.1002/anie.198501351
Abstract
The first example of a nitrogen‐containing crown ether acting as both a first and second sphere ligand towards a transition metal is found in the rhodium complex 1. This complex contains a crystallographic center of symmetry and is stabilized by intramolecular hydrogen bridges. equation imageKeywords
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