A Theory of Cooperative Phenomena. II. Equation of States for Classical Statistics
- 1 October 1951
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 19 (10) , 1230-1241
- https://doi.org/10.1063/1.1748002
Abstract
A method of obtaining the equation of state of a classical assembly through the solid, liquid, and gas phases based on the order-disorder concept is explained. At first, the method is illustrated on an imaginary two-dimensional model. Next, the general procedure to increase the number of interstitial sublattices to infinity is explained for a one-, two-, and three-dimensional lattice. In the one-dimensional case, the present method proves to be identical with Gürsey's rigorous solution. An approximate treatment for the solid state is added.Keywords
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