Iron Pentacarbonyl as a Precursor for Molecule-Based Magnets: Formation of Fe[TCNE]2(Tc= 100 K) and Fe[TCNQ]2(Tc= 35 K) Magnets
- 28 March 2002
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 41 (8) , 1996-1997
- https://doi.org/10.1021/ic011288b
Abstract
The reaction of tetracyanoethylene (TCNE) and 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) with Fe(CO)5 leads to formation of magnetically ordered materials of Fe[TCNE]2 (Tc = 100 K) and Fe[TCNQ]2 (Tc = 35 K) composition, respectively. In contrast, the reaction with 1,2-dichloro-5,6-dicyanobenzoquinone (DDQ) leads to a paramagnetic material.Keywords
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