Synthesis and Reactivity of the Unusual Five-Coordinate Hydrido−Hydroxo Complex OsH(OH)(CO)(PiPr3)2
- 1 August 1997
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 16 (17) , 3828-3836
- https://doi.org/10.1021/om970270z
Abstract
No abstract availableKeywords
This publication has 66 references indexed in Scilit:
- Direct Observation of OH Reductive Elimination from IrIII ComplexesAngewandte Chemie International Edition in English, 1995
- Reactions of RuHCl(CO)(PiPr3)2 with Alkyn-1-ols: Synthesis of Ruthenium(II) Hydroxyvinyl and Vinylcarbene ComplexesOrganometallics, 1994
- Syntheses and crystallographic characterizations of ruthenium complexes Ru4(CO)8(.mu.3-C6H2R2O2)2 (R = H, tert-Bu), complexes containing 1,2-semiquinone ligands which bridge through oxygen and .eta.6-C6 ringsOrganometallics, 1994
- Synthesis and reactivity of an iridium hydroxo complex. Insertion of ethylene into a metal-oxygen bondJournal of the American Chemical Society, 1993
- Insertion reaction of acetone-d6 into the osmium-hydrogen bond of [OsHCl(CO)(P-iso-Pr3)2]: experimental evidence for the hydrogen-transfer mechanism from alcohols to ketonesInorganic Chemistry, 1991
- Synthesis of N,N-dialkylcarbamato complexes of Group 4 metals (Ti, Zr, Hf) by the metal chloride–NHR2–CO2system (R = Et or Pri): crystal and molecular structure of [Hf(O2CNPri2)4]J. Chem. Soc., Dalton Trans., 1991
- Coordination of H2 and O2 to [OsHCl(CO)(PiPr3)2]: A Catalytically Active M(η2‐H2) ComplexAngewandte Chemie International Edition in English, 1988
- Activation of water molecule. 5. Rhodium(I) hydride catalyzed water gas shift reaction. Identification of the elemental reactions comprising the catalytic cyclesJournal of the American Chemical Society, 1981
- Hydration and reduction of carbon dioxide by rhodium hydride compounds. Preparation and reactions of rhodium bicarbonate and formate complexes, and the molecular structure of RhH2(O2COH)(P(i-Pr)3)2Journal of the American Chemical Society, 1979
- Complete kinetic analysis of thermal stereomutations of (+)-(1S,2S,3S)-r-1-cyano-t-2-phenyl-1,c-3-dideuteriocyclopropaneJournal of the American Chemical Society, 1978