Controlling carbon monoxide binding at di-iron units related to the iron-only hydrogenase sub-site
- 16 November 2007
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 5,p. 606-608
- https://doi.org/10.1039/b712805c
Abstract
Carbon monoxide binding by displacement of a pendant hemi-labile ligand at a di-iron site can be substantially ‘switched-on’ via a ligand protonation pathway which is competitive with metal-metal bond protonation.Keywords
This publication has 16 references indexed in Scilit:
- Evidence for the Formation of Terminal Hydrides by Protonation of an Asymmetric Iron Hydrogenase Active Site MimicInorganic Chemistry, 2007
- Electropolymeric materials incorporating subsite structures related to iron-only hydrogenase: active ester functionalised poly(pyrroles) for covalent binding of {2Fe3S}-carbonyl/cyanide assembliesChemical Communications, 2007
- An insight into the protonation property of a diiron azadithiolate complex pertinent to the active site of Fe-only hydrogenasesChemical Communications, 2006
- Characterization of a Diferrous Terminal Hydride Mechanistically Relevant to the Fe-Only HydrogenasesJournal of the American Chemical Society, 2005
- Iron-only hydrogenase: Synthetic, structural and reactivity studies of model compoundsCoordination Chemistry Reviews, 2005
- Synthesis of the H-cluster framework of iron-only hydrogenaseNature, 2005
- Electron Transfer at a Dithiolate-Bridged Diiron Assembly: Electrocatalytic Hydrogen EvolutionJournal of the American Chemical Society, 2004
- All-iron hydrogenase: synthesis, structure and properties of {2Fe3S}-assemblies related to the di-iron sub-site of the H-clusterElectronic supplementary information (ESI) available: crystal and structure refinement data for complexes 4a, 4b and 5a. See http://www.rsc.org/suppdata/dt/b2/b209690k/Dalton Transactions, 2003
- The Di-Iron Subsite of All-Iron Hydrogenase: Mechanism of Cyanation of a Synthetic {2Fe3S}–Carbonyl AssemblyChemistry – A European Journal, 2002
- Mechanisms of formic acid, methanol, and carbon monoxide electrooxidation at platinum as examined by single potential alteration infrared spectroscopyJournal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1988