Resolution, optical rotatory dispersion, and absolute configuration of 1,3‐bis(2‐piperidyl)propan‐2‐one (anaferine)
- 1 January 1971
- journal article
- research article
- Published by Wiley in Recueil des Travaux Chimiques des Pays-Bas
- Vol. 90 (12) , 1326-1330
- https://doi.org/10.1002/recl.19710901207
Abstract
(±)‐1,3‐Bis(2‐piperidyl)propan‐2‐one was resolved with the aid of the enantiomeric 6,6′‐dinitrobiphenyl‐2,2′‐dicarboxylic acids. Both optical rotatory dispersion measurements and chemical correlation showed the laevo‐rotatory compound to be (‐)‐(R,R)‐1,3‐bis(2‐piperidyl)propan‐2‐one, (‐)‐anaferine.Keywords
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